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David Lacroix

Professor at Université de Lorraine

Université de Lorraine
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Positions (1)

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David Lacroix

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Université de Lorraine

This PhD position at Université de Lorraine focuses on photothermal investigations of thermal transport in phase-change nanocomposites for energy storage systems. The project addresses a critical challenge in thermal energy storage (TES): the low thermal conductivity of phase-change materials (PCMs), which limits the efficiency of heat-charging and discharging in storage devices. By embedding PCMs within nanostructured solid matrices, such as porous silicon, the research aims to enhance effective thermal properties and understand the complex thermal transport behavior, especially near the phase-change temperature. The main objective is to develop and apply advanced non-contact photothermal and photoacoustic techniques for quantitative characterization of thermal transport in PCM-based nanocomposites. The focus is on the solid–liquid phase-transition regime, extracting effective thermal diffusivity and conductivity, and establishing correlations between confinement effects, phase-change behavior, and macroscopic thermal performance. Model systems will use porous silicon matrices infiltrated with n-alkane PCMs (e.g., hexadecane), and phase-change properties will be studied using Differential Scanning Calorimetry (DSC) and Raman spectroscopy to probe local structural and phase evolution under confinement. The PhD student will join LEMTA (Laboratoire Énergies & Mécanique Théorique et Appliquée, UMR 7563), a joint research unit of Université de Lorraine and CNRS, and become part of the TEMIN (Thermal Engineering at Micro- and Nano-scales) team. Supervision will be provided by Prof. David Lacroix and Dr. Mykola Isaiev. LEMTA offers a unique experimental environment with access to photothermal and photoacoustic techniques, Raman thermometry, infrared thermography, thermoreflectance methods, and scanning thermal microscopy. The project is embedded in a strong international collaboration with Taras Shevchenko National University of Kyiv, enabling complementary atomistic simulations of thermal transport in confined PCMs. Applicants should have a Master’s degree (or equivalent) in physics, materials science, thermal engineering, or a closely related field. Essential skills include knowledge of heat transfer and thermal transport properties, experimental experience or strong interest in thermal characterization techniques, proficiency in data analysis and modeling using Python and/or MATLAB, and basic knowledge of optics and electronics relevant to experimental setups. Experience with photothermal or photoacoustic techniques, phase-change materials, and non-contact thermal measurements (Raman, IR, thermoreflectance) is highly desirable. To apply, candidates should submit their application via the academic positions portal, including a CV, cover letter, and supporting documents. For further information, applicants may contact Prof. David Lacroix or Dr. Mykola Isaiev. The position offers a stimulating research environment, access to state-of-the-art facilities, and opportunities for international collaboration in the field of thermal energy storage and nanocomposite materials.

Articles (14)

Year:

2024

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2024

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2024

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2024

In the present work, we demonstrate the ability of a technique based on Monte Carlo resolution of the Boltzmann transport equation associated to the Green–Kubo autocorrelation of the phonon heat flux to predict, at thermal equilibrium, the thermal conductivity tensor of nanoporous structures. This methodology, which is derived from a former work [D. Lacroix, M. Isaiev, G. Pernot, Phys. Rev. B 104, 165 202 (2021)] developed in the case of bulk systems, is used to predict thermal transport properties of Si porous matrices and Si phononic membranes at room temperature. A broad range of porosities and different pore network organizations are considered. Our results are compared to available experimental data and former modeling techniques. In addition, analytical models based on the phonon mean free path are detailed and compared to numerical simulations.

Year:

2023

This paper studies thermal transport in nanoporous silicon with a significant specific surface area. First, the equilibrium molecular dynamics approach was used to obtain the dependence of thermal conductivity on a specific surface area. Then, a modified phonon transport kinetic theory-based approach was developed to analyze thermal conductivity. Two models were used to evaluate the phonon mean free path in the porous materials. The first model assumes that the dependence of the mean free path only relies on the specific surface area, and the second one also considers the mean free path variation with the porosity. Both approaches approximate molecular dynamics data well for the smaller porosity values. However, the first model fails for highly porous matrixes, while the second one matches well with molecular dynamics simulations across all considered ranges of the porosities. This work illustrates that the phonon mean free path dependence with the porosity/volume fraction of composite materials is essential for describing thermal transport in systems with significant surface-to-volume ratio.

Year:

2023

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2023

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2023

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2022

Year:

2022

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2021

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2021

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2021

Year:

2021

Collaborators (16)

Richard Dennis

World Maritime University

SWEDEN
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Maria Bałazińska

Central Mining Institute

POLAND
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Manfred Paier

AIT Austrian Institute of Technology GmbH

AUSTRIA
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Guillaume Castanet

Université de Lorraine

FRANCE
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Valeria Jana Schwanitz

Professor

Høgskulen på Vestlandet - Campus Sogndal

NORWAY
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Nikola Vasiljevic

Technical University of Denmark

DENMARK
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Konstantinos Termentzidis

-

FRANCE
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Vladimir Lysenko

-

FRANCE
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Demet Suna

AIT Austrian Institute of Technology GmbH

AUSTRIA
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Jessy Paterson

University of California, Berkeley

UNITED STATES
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M. Isaiev

Université de Lorraine

FRANCE
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Michael Barber

Austrian Institute of Technology

AUSTRIA
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Nicolas Stein

Université de Lorraine

FRANCE
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August Wierling

-

NORWAY
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Malgorzata Markowska

Central Mining Institute

POLAND
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Olivier Bourgeois

Institut NÉEL

FRANCE
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