Gert Salentijn
associate professor
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About
Gert Salentijn is an associate professor at Wageningen University in the Netherlands. His research focuses on advanced analytical methods, including NIR spectroscopy and microfluidic technologies, as well as techniques for detecting allergens and contaminants in food products. Recent publications highlight his work on portable sample processing and the characterization of various compounds using innovative methods and materials.
Articles (20)
Rim‐Based Binding of Perfluorinated Acids to Pillararenes Purifies Water
Per‐ and polyfluoroalkyl substances (PFAS) pose a rapidly increasing global problem as their widespread use and high stability lead worldwide to water contamination, with significant detrimental health effects. [1] Supramolecular chemistry has been invoked to develop materials geared towards the specific capture of PFAS from water, [2] to reduce the concentration below advisory safety limits (e.g., 70 ng/L for the sum of perfluorooctane sulfonic acid, PFOS and perfluorooctanoic acid, PFOA). Scale‐up and use in natural waters with high PFAS concentrations has hitherto posed a problem. Here we report a new type of host–guest interaction between deca‐ammonium‐functionalized pillar[5]arenes (DAF−P5s) and perfluoroalkyl acids. DAF−P5 complexes show an unprecedented 1 : 10 stoichiometry, as confirmed by isothermal calorimetry and X‐ray crystallographic studies, and high binding constants (up to 10 6 M −1 ) to various polyfluoroalkyl acids. In addition, non‐fluorinated acids do not hamper this process significantly. Immobilization of DAF−P5s allows a simple single‐time filtration of PFAS‐contaminated water to reduce the PFOS/PFOA concentration 10 6 times to 15–50 ng/L level. The effective and fast (<5 min) orthogonal binding to organic molecules without involvement of fluorinated supramolecular hosts, high breakthrough capacity (90 mg/g), and robust performance (>10 regeneration cycles without decrease in performance) set a new benchmark in PFAS‐absorbing materials.
Year:
2024
Collaborators (8)
Wing Cheung Mak
Associate Professor and Senior Lecturer
Linköping University
Laura Righetti
Assistant Professor in Analytical Chemistry
Wageningen University & Research
Stephan Freitag
TU Wien
Saer Samanipour
Assistant Professor
University of Amsterdam
Karen Rafferty
Queen's University Belfast
Gabriele Dr Kociok-Köhn
University of Bath
Han Zuilhof
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Georgina Ross
Chief Technology Officer
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