Annalisa Vacca

Microbial fuel cells (MFCs) are considered promising energy sources whereby chemical energy is converted into electricity via bioelectrochemical reactions utilizing microorganisms. Several factors affect MFC performance, including cathodic reduction of oxygen, electrode materials, cell internal and external resistances, and cell design. This work describes the effect of the catalyst coating in the air-cathode membrane electrode assembly (MEA) for a microbial fuel cell (MFC) prepared via electrodeposition of manganese oxide. The characterization of the synthesized air-cathode MFC, operating in a continuous mode, was made via electrochemical impedance spectroscopy (EIS) analyses for the determination of the intrinsic properties of the electrode that are crucial for scalability purposes. EIS analysis of the MFCs and of the MEA reveals that the anode and cathode contribute to polarization resistance by about 85% and 15%, respectively, confirming the high catalytic activity of the Mn-based air cathode. The maximum power density of the Mn-based cathode is about 20% higher than that recorded using a Pt/C electrode.