Catherine Cazin

Professor

Ghent University

Belgium

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Dr. Catherine Cazin is a Professor at Ghent University in Belgium. Her research focuses on the synthesis and applications of N-heterocyclic carbene metal complexes, with recent publications exploring their roles in catalysis and anticancer activity. She employs advanced techniques including machine learning to optimize catalysis processes, particularly in C–N bond-forming reactions and amide reductions.

Catherine Cazin

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Articles (19)

Electrochemical synthesis of palladium N-heterocyclic carbene (NHC) complexes

Investigation of the in vitro anticancer potential of bis(imino)acenaphthene–N-heterocyclic carbene transition metal complexes revealed TrxR inhibition and triggering of immunogenic cell death (ICD) for allyl palladates

[Cu(NHC)(OR)] (R = C(CF3)3) complexes for N–H and S–H bond activation and as pre-catalysts in the Chan–Evans–Lam reaction

Continuous Flow Synthesis of Group 11 Metal‐NHC Complexes [M(IPr)(OC(H)(CF3)2)] (with M=Cu, Ag and Au)

Impact of the N-Heterocyclic Carbene (NHC) Ligand on the trans-[Pd(NHC)(NH2nBu)Cl2] Precatalyst Architecture in C–N Bond-Forming Reactions

A simply accessible organometallic system to gauge electronic properties of N-heterocyclic carbenes

Machine learning directed discovery and optimisation of a platinum-catalysed amide reduction

The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions

Suzuki–Miyaura Cross-Coupling of Amides by N–C Cleavage Mediated by Air-Stable, Well-Defined [Pd(NHC)(sulfide)Cl2] Catalysts: Reaction Development, Scope, and Mechanism

Learning Green Chemistry Principles by Comparing Three Synthetic Routes to a Copper-NHC (NHC = N-heterocyclic carbene) Complex

Deep Red to Near-Infrared Light-Controlled Ruthenium-Catalyzed Olefin Metathesis

An air-stable [Cu(NHC)(OR)] (R = C(H)(CF3)2) complex for C–H, N–H and S–H bond activation

Synthesis, characterization, and reactivity of [Pd(phosphine)(py)Cl2] (PEPPSI) and [Pd(phosphine)Cl2]2 complexes

Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route

Buchwald–Hartwig Amination and C–S/S–H Metathesis of Aryl Sulfides by Selective C–S Cleavage Mediated by Air- and Moisture-Stable [Pd(NHC)(μ-Cl)Cl]2 Precatalysts: Unified Mechanism for Activation of Inert C–S Bonds

Buchwald-Hartwig Amination and C-S/S-H Metathesis of Aryl Sulfides by Selective C-S Cleavage Mediated by Air- and Moisture- Stable [Pd(NHC)(mu-Cl)Cl]2 Precatalysts: Unified Mechanism for Activation of Inert C-S Bonds

A Versatile Palladium Synthon: [Pd(NHC)(PhC≡CPh)]**

A Versatile Palladium Synthon: [Pd(NHC)(PhC equivalent to CPh)]

Synthetic Access to Aromatic α-Haloketones

Collaborators (11)

Klaartje De Buysser

David Liptrot

Steven Nolan

Luigi Cavallo

Andreas Simoens

Christian V. Stevens

Sylwia Ostrowska

Fady Nahra

Albert Poater

Valentina Gandin

Michal Szostak

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