Claudio Ampelli

Highly ordered TiO2 nanotube (NT) arrays grown on Ti mesh and Ti foil were successfully prepared by a controlled anodic oxidation process and tested for water photo-electrolysis. Electrochemical impedance spectroscopy (EIS), combined with other electrochemical techniques (cyclic voltammetry and chronoamperometry) in tests performed in the dark and under illumination conditions, was used to correlate the photoactivity to the specific charge transfer resistances associated with a 3D (mesh) or 2D (foil) geometry of the support. The peculiar structure of the nanotubes in the mesh (with better light absorption and faster electron transport along the nanotubes) strongly impacts the catalytic performances under illumination. H2 production and current density in water photo-electrolysis were over three times higher with the TiO2NTs/Ti mesh, compared to the foil in the same conditions. The results obtained by the EIS technique, used here for the first time to directly compare TiO2 nanotubes on two different supports (Ti foil and Ti mesh), led to a better understanding of the electronic properties of TiO2 nanotubes and the effect of a specific support on its photocatalytic properties.

In this contribution, a 25 GHz planar antenna, designed and realized in microstrip technology, is exploited as a lightweight and compact liquid sensor. The high working frequency allows minimization of the sensor dimension. Moreover, particular attention was paid to keeping the design cost low. Indeed, the frequency of 25 GHz is widely exploited for many applications, e.g., up to the last decade concerning radars and, recently, 5G technology. Available commercial antennas allowed minimization of the effort that is usually required to design the microstrip sensor. The antenna was in-house realized, and the microstrip Cu conductor was modified through controlled anodic oxidation in order to enhance the sensing features. The sensor capability of detecting the presence and concentration of ethanol in water was experimentally demonstrated. In detail, a sensitivity of 0.21 kHz/(mg/L) and an average quality factor of 117 were achieved in a very compact size, i.e., 18 mm × 19 mm, and in a cost-effective way. As a matter of fact, the availability of devices able to collect data and then to send the related information wirelessly to a remote receiver represents a key feature for the next generation of connected smart sensors.