Demyan Prokopchuk

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Assistant Professor

Rutgers University

United States

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Demyan Prokopchuk is an Assistant Professor at Rutgers University in the United States. His research primarily focuses on organometallic chemistry, particularly in the areas of thermochemistry, bond activation, and the electrochemical properties of transition metal complexes. Recent publications include studies on the kinetics and mechanisms of ligand interactions and hydration structures of metal aqua ions. His work contributes to a deeper understanding of redox chemistry and catalysis in complex chemical systems.

Recent Grants

Grant: Close

NSF-DFG Echem: CAS: Synergistic Experimental and Computational Approaches to Designing Electrocatalysts with Proton-Responsive Ligand Architectures

Open Date: 2021-08-01

Close Date: 2024-07-31

Grant: Close

MRI: Acquisition of a Single Crystal X-ray Diffractometer

Open Date: 2020-08-15

Close Date: 2023-07-31

Grant: Close

Small Molecule Activation with Fe and Ru: Synthesis and Computational Analysis of Water Splitting With Ru-based Metal Complexes; DFT Study Into Asymmetric Transfer Hydrogenation Using Fe Complexes

Open Date: 2013-04-01

Close Date: 2014-03-31

Grant: Close

Small Molecule Activation with Fe and Ru: Synthesis and Computational Analysis of Water Splitting With Ru-based Metal Complexes; DFT Study Into Asymmetric Transfer Hydrogenation Using Fe Complexes

Open Date: 2012-04-01

Close Date: 2013-03-31

Grant: Close

Small Molecule Activation with Fe and Ru: Synthesis and Computational Analysis of Water Splitting With Ru-based Metal Complexes; DFT Study Into Asymmetric Transfer Hydrogenation Using Fe Complexes

Open Date: 2011-04-01

Close Date: 2012-03-31

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2022

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2021

Collaborators (2)

Jenny Lockard

Rutgers, The State Univ. of NJ

UNITED STATES

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Roger Lalancette

Professor

Rutgers University

UNITED STATES

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Demyan Prokopchuk

Research Interests

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Recent Grants

Articles (16)

Expanding the PCET Thermochemistry of CpN3: N–H Bond Strengths of Metal-Free CpN3 Molecules and the Influence of Fe(CO)3 Coordination

A 100,000-Fold Increase in C–H Bond Acidity Gives Palladium a Key Advantage in C(sp3)–H Activation Compared to Nickel

Regioselective access to B–N Lewis pair-functionalized anthracenes: mechanistic studies and optoelectronic properties

Multisite Ligand Noninnocence of (CpN3)Fe(CO)3+ with Exogenous Hydride Donors: Kinetics and Mechanism

Pushing the Limits of Organometallic Redox Chemistry with an Isolable Mn(−I) Dianion

Unraveling the Hydration Shell Structure and Dynamics of Group 10 Aqua Ions

Structural and electrochemical analysis of FeCp* complexes supported by a borate-bridged dicarbene ligand

Accessing Ni(0) to Ni(IV) via nickel–carbon–phosphorus bond reorganization

“Catch and release” of the CpN3 ligand using cobalt: dissociation, protonation, and C–H bond thermochemistry

Cyclopentadienyl ring activation in organometallic chemistry and catalysis

Putting a new spin on imido chemistry with an FeII dicarbene complex

Essential Roles of Cp Ring Activation and Coordinated Solvent During Electrocatalytic H2 Production with Fe(CpN3) Complexes

Electronic Effects of Aminoindenyl Ligands Coordinated to Manganese: Structures and Properties of a Mn0 Metalloradical and Bimetallic Mn–I/MnI Adduct

Coordination-Induced Weakening of a C(sp3)–H Bond: Homolytic and Heterolytic Bond Strength of a CH–Ni Agostic Interaction

A redox-active Mn(0) dicarbene metalloradical

Ligand Protonation at Carbon, not Nitrogen, during H2 Production with Amine-Rich Iron Electrocatalysts

Collaborators (2)

Jenny Lockard

Roger Lalancette

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