We describe herein the direct electrophilic γ‐trifluoromethylthiolation and γ‐methylthiolation of enals, via the in situ formation of the corresponding silyl dienol ether. This one‐pot process is carried out under simple and mild reaction conditions and is compatible with a variety of functional groups.

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Year:

2024

Photocatalytic α‐Difluoroalkoxyketones Synthesis via Radical Intermolecular Alkoxylation of Difluoroenol Silyl Ethers

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Year:

2024

Photocatalyzed One‐Pot Selective Synthesis of γ‐(per)fluoroalkenylated α,β‐Unsaturated Carbonyl Compounds

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Year:

2024

Light‐Driven Synthesis and Functionalization of Bicycloalkanes, Cubanes and Related Bioisosteres

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Year:

2024

Light‐Driven Synthesis and Functionalization of Bicycloalkanes, Cubanes and Related Bioisosteres

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Year:

2024

Electrophilic Fluorination of Silyl Dienol Ethers: a General and Selective Access to γ‐Fluoro Enals

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Year:

2024

From perfluoroalkyl aryl sulfoxides to ortho thioethers

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Year:

2024

Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis

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Year:

2024

Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis

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Year:

2024

Perfluoroalkyl Selenoxides, Selenones and Selenoximines: General Preparation and Properties

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Year:

2023

Perfluoroalkyl Selenoxides, Selenones and Selenoximines: General Preparation and Properties

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Year:

2023

Recent Uses of Photogenerated Oxygen-Centered Radicals in Intermolecular C–O Bond Formation

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Year:

2023

Highly selective γ-alkoxylation, γ-amination and γ-alkylation of unbiased enals by means of photoredox catalysis

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Year:

2023

Remote Radical Trifluoromethylation: A Unified Approach to the Selective Synthesis of γ-Trifluoromethyl α,β-Unsaturated Carbonyl Compounds

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Year:

2022

Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures

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Year:

2022

Vinylic Trifluoromethylselenolation via Pd‐Catalyzed C−H Activation

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Year:

2022

Radical α-Trifluoromethoxylation of Ketones under Batch and Flow Conditions by Means of Organic Photoredox Catalysis

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Year:

2021

Intermolecular C–O Bond Formation with Alkoxyl Radicals: Photoredox-Catalyzed α-Alkoxylation of Carbonyl Compounds

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Year:

2021

Synthesis of Nitrogen- and Oxygen-Containing Heterocycles by Prins Cyclization in Continuous Flow

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Year:

2021

Collaborators (6)

Xavier Moreau

Institut Lavoisier de Versailles

FRANCE

Thierry Billard

FRANCE

Luca Dell'Amico

Assistant Professor

University of Padova

ITALY

elsa anselmi

Institut Lavoisier de Versailles

FRANCE

Sébastien Floquet

Université Paris-Saclay

FRANCE

Samir Messaoudi

Université Paris-Saclay

FRANCE

Guillaume Dagousset

Research Interests

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Articles (26)

Radical photochemical difluorosulfoximination of alkenes and propellanes

Advances in radical remote γ-functionalization of α,β-unsaturated carbonyl compounds

Multigram-Scale Synthesis and Study of Reactivity of Two Difluoromethylating Reagents Based on Sulfoximine Skeletons

Les radicaux alcoxy : de nouvelles opportunités pour la formation de liaisons C–O

Metal‐Free Multicatalytic Decarbonylation of Aldehydes Driven by Light

Metal‐Free Multicatalytic Decarbonylation of Aldehydes Driven by Light

Site‐Selective γ‐Trihalomethylation and γ‐Dihalomethylidenation of Silyl Dienol Ethers under Organophotoredox Catalysis

One‐Pot Regioselective γ‐Trifluoromethylthiolation and γ‐Methylthiolation of Enals

Photocatalytic α‐Difluoroalkoxyketones Synthesis via Radical Intermolecular Alkoxylation of Difluoroenol Silyl Ethers

Photocatalyzed One‐Pot Selective Synthesis of γ‐(per)fluoroalkenylated α,β‐Unsaturated Carbonyl Compounds

Light‐Driven Synthesis and Functionalization of Bicycloalkanes, Cubanes and Related Bioisosteres

Light‐Driven Synthesis and Functionalization of Bicycloalkanes, Cubanes and Related Bioisosteres

Electrophilic Fluorination of Silyl Dienol Ethers: a General and Selective Access to γ‐Fluoro Enals

From perfluoroalkyl aryl sulfoxides to ortho thioethers

Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis

Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis

Perfluoroalkyl Selenoxides, Selenones and Selenoximines: General Preparation and Properties

Perfluoroalkyl Selenoxides, Selenones and Selenoximines: General Preparation and Properties

Recent Uses of Photogenerated Oxygen-Centered Radicals in Intermolecular C–O Bond Formation

Highly selective γ-alkoxylation, γ-amination and γ-alkylation of unbiased enals by means of photoredox catalysis

Remote Radical Trifluoromethylation: A Unified Approach to the Selective Synthesis of γ-Trifluoromethyl α,β-Unsaturated Carbonyl Compounds

Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures

Vinylic Trifluoromethylselenolation via Pd‐Catalyzed C−H Activation

Radical α-Trifluoromethoxylation of Ketones under Batch and Flow Conditions by Means of Organic Photoredox Catalysis

Intermolecular C–O Bond Formation with Alkoxyl Radicals: Photoredox-Catalyzed α-Alkoxylation of Carbonyl Compounds

Synthesis of Nitrogen- and Oxygen-Containing Heterocycles by Prins Cyclization in Continuous Flow

Collaborators (6)

Xavier Moreau

Thierry Billard

Luca Dell'Amico

elsa anselmi

Sébastien Floquet

Samir Messaoudi

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