I. S. Yehia

Streptomycin was chosen as the test species, and MgO@graphene nanocomposites were created and assessed for their catalytic activity towards the breakdown of 4-NP. As a new catalyst with strong catalytic activity and good stability, MgO@graphene was used. It was discovered that this catalyst’s catalytic activity was much increased in an acidic environment. It is suggested that the degradation mechanism is caused by MgO@graphene nanocomposites reacting with dissolved oxygen. This further demonstrates the obvious significance of graphene in serving as the MgO nanocatalyst’s support. XRD results indicated that the majority of G species in MgO@ (0.25 g) G more strongly interacted with the MgO surface. The doped catalyst MgO@ (0.25 g) G reached its steady state activity faster than the other catalysts. The degree of MgO@G interaction decreased in the following S 4 > S[Formula: see text] > S[Formula: see text] > S[Formula: see text] > S[Formula: see text] > S 5 > S[Formula: see text] > S[Formula: see text]. High degradation rate constants were found, and the amounts of streptomycin and 4-nitrophenol vary exponentially over time. It was demonstrated that, in most situations, the pseudo-first- order equation fits the degradation kinetics. Hence, in degrading systems, MgO NPs@Graphene nanostructures are thought to be a very effective and promising catalyst.

In this study, laser-assisted chemical bath synthesis (LACBS) was used to prepare pure and Ag-doped ZnO submicron structures using a simplified hydrothermal approach that did not require a catalyst. The photocatalytic degradation of Methylene Blue was investigated under blue laser irradiation (λ = 444.5 nm and I = 8000 lx). The doping concentration varied (2%, 4%, 6%, 8%, tando 10%) and was prepared by LACBS using a continuous blue laser (P = 7 W, λ = 444.5 nm) for the first time. XRD, FE-SEM, EDX, and UV-Vis investigated the characteristics of the samples produced by the LACBS. ZnO: Ag(10%) submicron flowers are essential in rapid photodegradation under blue laser irradiation. The high surface area and catalytic activity of the prepared Ag-decorated ZnO are attributed to this improved photocatalytic activity. Using UV-visible spectroscopy, the photocatalytic efficiency was determined from the absorption spectra. The separation of photo-generated electron-hole pairs was facilitated, and the absorption edge of the hybrid submicron structures shifted into the visible spectrum region due to a combination of the Ag plasmonic effect and surface imperfections in ZnO. Effective visible light absorption was achieved via band-edge tuning, which increased the ZnO:Ag submicron structures’ ability to degrade dyes.