Jean-Marc Planeix

The synthesis of two ligands bearing two terminal catecholate binding sites connected by an oligo(ethyleneglycol) bridge of two distinct lengths and their self‐assembly upon boron coordination and alkali cation binding (M=Li, Na, K, Cs) are reported. Attempts to synthesize positional isomers of the ligands are also described. Binding of the four alkali cations M + through M−O interactions was studied depending on the length of the oligo(ethyleneglycol) chain in solution by 1 H and DOSY NMR, mass spectrometry (MS) and in the solid‐state by X‐ray diffraction (XRD) on single crystals. MS spectrometry as well as 1 H NMR revealed the presence of monomeric and oligomeric spiroborate compounds. Two monomeric macrocycles could be characterized by XRD, entrapping either lithium or cesium cations within the spiroborate macrocycle.

Supramolecular functionalization of MOFs (SUM-103): application to the extraction of pollutants from water.