John Gladysz

Distinguished Professor and Dow Chair in Chemical Invention

Texas A&M University

United States

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John Gladysz is a Distinguished Professor and Dow Chair in Chemical Invention at Texas A&M University, USA. His research focuses on enantiopure chiral complexes, synthetic methodologies, and the catalytic applications of various chemical compounds, particularly involving platinum and rhenium. Recent publications highlight advancements in enantioselective catalysis and the structural characterization of complex compounds, contributing significantly to the fields of organic and inorganic chemistry.

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2022

Collaborators (2)

Michael B. Hall

Texas A&M University

UNITED STATES

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Karsten Meyer

Chair, Full Professor

Friedrich-Alexander Universität Erlangen-Nürnberg

GERMANY

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John Gladysz

Research Interests

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Articles (20)

Enantiopure chiral platinum(II) bis(diamine) complexes [Pt((S,S)-1,2-diphenylethylenediamine)2]2+ 2X–: Syntheses, structures, and enantioselective catalysis of additions of 1,3-dicarbonyl compounds to nitroalkenes and dialkyl azodicarboxylates

Enantiopure Phosphine Oxides with Electron‐Rich Chiral Rhenium Stereocenters: Syntheses, Structures, and Brønsted Basicities

Syntheses, Structures, Reactivity, and Catalytic Applications of Enantiopure Rhenium-Containing P-Stereogenic Phosphonium Salts, Phosphines, Phosphine Boranes, and Phosphine Oxides

Frontiers in the Crystallographic Characterization of Extended Conjugated Polyynes: New Structures of Diplatinum Adducts and a Literature Survey

Syntheses and structures of chiral rhenium-containing phosphonium salts and phosphines with ReCH2P̈Ar2 or ReCH(R)P̈Ar2 linkages; enantioselective catalysis of intramolecular Morita–Baylis–Hillman and Rauhut–Currier reactions

A Caged Neutral 17-Valence-Electron Iron(I) Radical [Fe(CO)2(Cl)(P((CH2)10)3P)]•: Synthetic, Structural, Spectroscopic, Redox, and Computational Studies

Platinum Elimination from Bis(triethylsilylpolyynyl) Complexes (n‐Bu2C(CH2PPh2)2)Pt((C≡C)nSiEt3)2 (n=2, 3) and Macrocycles Comprised of Four L2Pt Corners and Four C≡CC≡CC≡C Linkers; An Approach to Cyclo[24]carbon

Synthetic Approaches to and Structures of Diplatinum Polyynediyl Complexes trans,trans‐[(C6F5)(R3P)2Pt(C≡C)nPt(PR3)2(C6F5)] With Odd Numbers of Triple Bonds; Avoiding Complicating Ethynediyl Extrusions

Revisiting the Early Days of Conjugated Polyyne Synthesis. Syntheses and Structures of Bis(triethylsilyl) Polyynediyl Adducts Et3Si(C C) SiEt3 Previously Regarded as Unisolable (n = 6, 8, 12)

Macrobicyclic Dibridgehead Di(trialkyl)pnictogens E((CH2)n)3E (E/n = As/10, As/12, As/14, Sb/14) and Their Cage-like Metal Complexes: Syntheses, Structures, and Homeomorphic Isomerizations

Gyroscope-Like Platinum(IV) Complexes of the Macrocyclic Dibridgehead Diphosphine P((CH2)14)3P

Building Blocks for Molecular Polygons Based on Platinum Vertices and Polyynediyl Edges

Shortwave Infrared Fluorofluorophores for Multicolor In Vivo Imaging**

Shortwave Infrared Fluorofluorophores for Multicolor In Vivo Imaging**

Square-Planar and Octahedral Gyroscope-Like Metal Complexes Consisting of Dipolar Rotators Encased in Dibridgehead Di(triaryl)phosphine Stators: Syntheses, Structures, Dynamic Properties, and Reactivity

Mechanism of Coupling of Methylidene to Ethylene Ligands in Dimetallic Assemblies; Computational Investigation of a Model for a Key Step in Catalytic C1 Chemistry

Azide- and Fluorine-Containing Polystyrenes as Potential ″Phosphine Sponges″ Based upon Staudinger Reactions: Application to the Phase Transfer Activation of Grubbs’ Catalyst

Tracking Energy Transfer across a Platinum Center

Rhodium(III) Werner Complexes with 1,2‐Diphenylethylenediamine Ligands: Syntheses, Structures, and Applications as Chiral Hydrogen Bond Donor Catalysts and Agents for Enantiomer Purity Determinations

Syntheses, Structures, Reactivities, and Dynamic Properties of Gyroscope-like Complexes Consisting of Rh(CO)(X) or Rh(CO)2(I) Rotators and Cage-like Trans Aliphatic Dibridgehead Diphosphine Stators

Collaborators (2)

Michael B. Hall

Karsten Meyer

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John Gladysz

Research Interests

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About

Articles (20)

Enantiopure chiral platinum(II) bis(diamine) complexes [Pt((S,S)-1,2-diphenylethylenediamine)2]2+ 2X–: Syntheses, structures, and enantioselective catalysis of additions of 1,3-dicarbonyl compounds to nitroalkenes and dialkyl azodicarboxylates

Enantiopure Phosphine Oxides with Electron‐Rich Chiral Rhenium Stereocenters: Syntheses, Structures, and Brønsted Basicities

Syntheses, Structures, Reactivity, and Catalytic Applications of Enantiopure Rhenium-Containing P-Stereogenic Phosphonium Salts, Phosphines, Phosphine Boranes, and Phosphine Oxides

Frontiers in the Crystallographic Characterization of Extended Conjugated Polyynes: New Structures of Diplatinum Adducts and a Literature Survey

Syntheses and structures of chiral rhenium-containing phosphonium salts and phosphines with ReCH2P̈Ar2 or ReCH(R)P̈Ar2 linkages; enantioselective catalysis of intramolecular Morita–Baylis–Hillman and Rauhut–Currier reactions

A Caged Neutral 17-Valence-Electron Iron(I) Radical [Fe(CO)2(Cl)(P((CH2)10)3P)]•: Synthetic, Structural, Spectroscopic, Redox, and Computational Studies

Platinum Elimination from Bis(triethylsilylpolyynyl) Complexes (n‐Bu2C(CH2PPh2)2)Pt((C≡C)nSiEt3)2 (n=2, 3) and Macrocycles Comprised of Four L2Pt Corners and Four C≡CC≡CC≡C Linkers; An Approach to Cyclo[24]carbon

Synthetic Approaches to and Structures of Diplatinum Polyynediyl Complexes trans,trans‐[(C6F5)(R3P)2Pt(C≡C)nPt(PR3)2(C6F5)] With Odd Numbers of Triple Bonds; Avoiding Complicating Ethynediyl Extrusions

Revisiting the Early Days of Conjugated Polyyne Synthesis. Syntheses and Structures of Bis(triethylsilyl) Polyynediyl Adducts Et3Si(C C) SiEt3 Previously Regarded as Unisolable (n = 6, 8, 12)

Macrobicyclic Dibridgehead Di(trialkyl)pnictogens E((CH2)n)3E (E/n = As/10, As/12, As/14, Sb/14) and Their Cage-like Metal Complexes: Syntheses, Structures, and Homeomorphic Isomerizations

Gyroscope-Like Platinum(IV) Complexes of the Macrocyclic Dibridgehead Diphosphine P((CH2)14)3P

Building Blocks for Molecular Polygons Based on Platinum Vertices and Polyynediyl Edges

Shortwave Infrared Fluorofluorophores for Multicolor In Vivo Imaging**

Shortwave Infrared Fluorofluorophores for Multicolor In Vivo Imaging**

Square-Planar and Octahedral Gyroscope-Like Metal Complexes Consisting of Dipolar Rotators Encased in Dibridgehead Di(triaryl)phosphine Stators: Syntheses, Structures, Dynamic Properties, and Reactivity

Mechanism of Coupling of Methylidene to Ethylene Ligands in Dimetallic Assemblies; Computational Investigation of a Model for a Key Step in Catalytic C1 Chemistry

Azide- and Fluorine-Containing Polystyrenes as Potential ″Phosphine Sponges″ Based upon Staudinger Reactions: Application to the Phase Transfer Activation of Grubbs’ Catalyst

Tracking Energy Transfer across a Platinum Center

Rhodium(III) Werner Complexes with 1,2‐Diphenylethylenediamine Ligands: Syntheses, Structures, and Applications as Chiral Hydrogen Bond Donor Catalysts and Agents for Enantiomer Purity Determinations

Syntheses, Structures, Reactivities, and Dynamic Properties of Gyroscope-like Complexes Consisting of Rh(CO)(X) or Rh(CO)2(I) Rotators and Cage-like Trans Aliphatic Dibridgehead Diphosphine Stators

Collaborators (2)

Michael B. Hall

Karsten Meyer

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Revisiting the Early Days of Conjugated Polyyne Synthesis. Syntheses and Structures of Bis(triethylsilyl) Polyynediyl Adducts Et3Si(C C) SiEt3 Previously Regarded as Unisolable (n = 6, 8, 12)