Juan A. Casares

Universidad de Valladolid

Spain

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Articles (6)

Year:

2022

Two monomeric copper( i ) complexes participate in the activation of an Ar–I bond. One of them weakens the C–I bond, while the other inserts in the bond. Paradoxically, only one copper( i ) complex participates in the breaking of stronger Ar–Br bonds.

Year:

2022

Year:

2022

Year:

2021

Year:

2021

Year:

2020

Collaborators (1)

Agusti Lledos

Professor

University of Barcelona

SPAIN

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Juan A. Casares

Research Interests

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Articles (6)

Copper(i) activation of C–X bonds: bimolecular vs. unimolecular reaction mechanism

Copper(<scp>i</scp>) activation of C–X bonds: bimolecular<i>vs.</i>unimolecular reaction mechanism

Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes

Transmetalation Reactions Triggered by Electron Transfer between Organocopper Complexes

Experimental study of the [ZnCl2(THF)2] catalyzed cis/trans-isomerization of [Pd(C6Cl2F3)Me(PPh3)2] and of the transmetalation of trans-[PdCl(C6Cl2F3)(PPh3)2] with [ZnMeCl(THF)2]

Experimental and DFT Study of the [AuAr(AsPh3)]-Catalyzed cis/trans Isomerization of [PdAr2(AsPh3)2] (Ar = C6F5 or C6Cl2F3): Alternative Mechanisms and Its Switch upon Pt for Pd Substitution

Collaborators (1)

Agusti Lledos

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