María Rodríguez‐Castillo

New luminescent heterometallopolymers [(Au‐C 6 F 5 ) m (AgOSO 2 CF 3 ) n (PVP)] with different Au:Ag molar ratios were synthesized. The luminescent emissions of these polymers are strongly dependent on the temperature, excitation wavelengths, and the Au(I):Ag(I) molar ratio. The incorporation of a precise amount of Ag(I) atoms in the backbone of [(Au‐C 6 F 5 ) m (PVP)] metallopolymer allows a controlled tuning of the emission energy in the green‐blue range.