Martin Oestreich

Professor

Technische Universität Berlin

Germany

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Professor Martin Oestreich serves at Technische Universität Berlin, Germany. His research areas encompass transition-metal-catalyzed reactions, including enantioconvergent C–C cross-coupling, and the synthesis of complex organic molecules utilizing novel methodologies. His recent publications highlight advancements in catalysts for allylic substitution, and the synthesis of azobenzenes, along with investigations into silylium ions and their applications in organic transformations.

Martin Oestreich

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Articles (30)

Directing Effects of Silyl and Germyl Groups in Transition‐Metal‐Catalyzed Allylic Substitution

Atroposelective Synthesis of Azobenzenes by Palladium-Catalyzed Cross-Coupling of Racemic Biaryl Triflates and Diazenyl Pronucleophiles

Nickel-Catalyzed Enantioconvergent C(sp3)–C(sp3) Cross-Coupling between α-Iodogermanes and Alkylzinc Reagents

Isolation of halogen-substituted silylium ions

Silylium-Ion-Promoted Formation of Methylenecyclobutenes by Formal (2 + 2) Cycloaddition of Allenylsilanes and Internal Alkynes

Kinetic Resolution of BINAMs by Stereoselective Copper-Catalyzed Dehydrogenative Si–N Coupling with Prochiral Dihydrosilanes

Dynamic Kinetic C(sp2)–Si Cross-Coupling with Si–B Reagents for the Atroposelective Construction of Unsymmetrical Heterobiaryls

Kinetic Resolution of Acyclic 1,3-Diols by Copper-Catalyzed Regioselective Dehydrogenative Si–O-Coupling

Photoredox-Catalyzed Transfer Aminochlorination of Unactivated Alkenes Using Oxime-Based Surrogates

One-Pot Sequential Alcohol Activation and Nickel-Catalyzed Cross-Electrophile Coupling with Chlorosilanes

Silylium-Ion-Initiated Twofold Halodealkylation of Fully Alkylated Silanes

Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides

Enantioselective Dearomatization of Pyridinium Salts by Copper‐Catalyzed C4‐Selective Addition of Silicon Nucleophiles

Enantioselektive Dearomatisierung von Pyridiniumsalzen durch kupferkatalysierte C4‐selektive Addition von Siliciumnukleophilen

Ring Contraction of Saturated Cyclic Amines and Rearrangement of Acyclic Amines Through Their Corresponding Hydroxylamines

Ring Contraction of Saturated Cyclic Amines and Rearrangement of Acyclic Amines Through Their Corresponding Hydroxylamines

Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides

Ni–H-Catalyzed Chemo- and Regioselective Hydroarylation of Vinylsilanes

Synthesis of a Cationic Cobalt–Selenolate Complex for Cooperative Sn–H Bond Activation: Solvent-Dependent Stereoselectivity in Alkyne Hydrostannylation

Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions

Fluoride-Catalyzed Arylation of α-(Trifluoromethyl)styrene Derivatives with Silicon-Masked, Functionalized Aryl Pronucleophiles

Generation of Silicon-Centered Stereogenicity by Chiral Counteranion-Directed Desymmetrization of Silanediols

The Two Faces of Carbenium Ions: Intermolecular Trapping of Prochiral Carbocations with Stereocontrol

Dehydrative Coupling of 1,1-Diarylalkenes and Cyclohexa-2,5-diene-1-carbaldehyde Derivatives Induced by a B(C6F5)3-Initiated [1,2]-Alkyl Migration

Regioselective Hydroalkylation of Vinyl- and Allylsilanes as Well as Vinylgermanes under Ni–H Catalysis

Discrimination of the Enantiotopic Faces of Structurally Unbiased Carbenium Ions Employing a Cyclohexadiene‐Based Chiral Hydride Source

Unterscheidung der enantiotopen Seiten von strukturell unvoreingenommenen Carbeniumionen unter Verwendung einer cyclohexadienbasierten, chiralen Hydridquelle

Atroposelective Silylation of 1,1′‐Biaryl‐2,6‐diols by a Chiral Counteranion Directed Desymmetrization Enhanced by a Subsequent Kinetic Resolution

Atropselektive Silylierung von 1,1′‐Biaryl‐2,6‐diolen mittels chiraler gegenaniondirigierter Desymmetrisierung und anschließender Verbesserung durch kinetische Racematspaltung

Palladium-Catalyzed Denitrogenative Cross-Coupling of Silicon-Masked, Aryl-Substituted Diazenes and Aryl Bromides

Collaborators (6)

Biping Xu

Martin Kaupp

Sebastian Kemper

Daniel Brösamlen

Hendrik Klare

Stefan Grimme

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