Micael S. Nascimento

Batteries are seen as a vital piece for actual carbon‐neutral world needs. However, as they basically operate through extremely exothermic electrochemical events, special attention must be paid to their thermal and volumetric constraints, where continuous and accurate monitoring is of great importance. Considering it, customized optical sensors, based on fiber Bragg gratings recorded in birefringent PANDA fibers (FBG‐PANDA), are developed and instrumented in a coiled configuration into a cylindrical Li‐ion battery (LiB) to simultaneously track temperature and radial strain during galvanostatic cycles, in three different battery locations, for the first time. The maximum temperature and radial strain variations are achieved in the middle and at the end of the discharge steps. This thermal behavior is correlated with the internal heat generation and transfer of thermal energy processes, with a tendency to accumulate in the LiB central zone.Good feasibility and reproducibility are observed in the optical sensor's performance and demonstrated that by operating as a multiparameter decouple system, they can decrease the complexity and intrusiveness in batteries, by using only one optical fiber line. The reported results are in accordance with the literature, indicating that such sensors could be consistently used for future applications regarding battery safety parameters sensing.