Takayoshi Arai

Japan

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Articles (12)

Year:

2024

Year:

2024

In a tris(pentafluorophenyl)borane [B(C 6 F 5 ) 3 ]‐catalyzed reaction of alkenes with cyanogen halides (XCN), BrCN proceeds in a cyanation/bromination manner, in which a cationic CN character is realized. The reaction using ICN switched the mode to iodination/cyanation for enamide substrates and electron‐enriched styrenes. The origin of the iodination/cyanation is the B(C 6 F 5 ) 3 ‐enhanced σ‐hole generated on ICN.

Year:

2023

Year:

2023

Year:

2023

Year:

2022

Year:

2022

Year:

2021

Year:

2021

Year:

2021

Year:

2020

Year:

2020

Collaborators (2)

Ayumi Furuse

Shinshu University

JAPAN

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Hayato Otsuka

Shinshu University

JAPAN

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Takayoshi Arai

Research Interests

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Articles (12)

Bis(imidazolidine)-Derived NCN Nickel-Pincer-Catalyzed Asymmetric Reactions

Nanoporosity changes of graphene oxide colloids on linkage-treatment with molecular linker and heating after the linkage-treating

Halogenation/Cyanation vs. Cyanation/Halogenation of Alkenes Using ICN and BrCN

Asymmetric para-Selective aza-Friedel–Crafts Reaction of Phenols Catalyzed by Bulky PyBidine-Ni(OAc)2

Asymmetric Friedel–Crafts-Type Reaction of 2-Vinylindoles to N-Boc Imines Using a Chiral Imidazolidine-Containing NCN-Pincer Pd Catalyst

Intermolecular Catalytic Asymmetric Iodoetherification of Unfunctionalized Alkenes

Chiral Aminomethylbinaphthol‐Catalyzed Diastereo‐ and Enantioselective Epoxidation of Trisubstituted Acrylonitriles

A Hypervalent Cyclic Dibenzoiodolium Salt as a Halogen‐Bond‐Donor Catalyst for the [4+2] Cycloaddition of 2‐Alkenylindoles

Chiral C2-Symmetric Aminomethylbinaphthol as Synergistic Catalyst for Asymmetric Epoxidation of Alkylidenemalononitriles: Easy Access to Chiral Spirooxindoles

Enantio- and diastereoselective double Mannich reaction of malononitrile with N-Boc imines using quinine-derived bifunctional organoiodine catalyst

Catalytic Asymmetric Chlorination of β-Ketoesters Using N-PFB-PyBidine-Zn(OAc)2

Catalytic Asymmetric Iodoesterification of Simple Alkenes

Collaborators (2)

Ayumi Furuse

Hayato Otsuka

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