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The University of Manchester

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PhD Studentship in Radicals and Reactive Intermediates in Heavy Main-Group Chemistry The University of Manchester in United Kingdom

Degree Level

PhD

Field of study

Chemistry

Funding

Available

Deadline

Dec 18, 2026

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Country

United Kingdom

University

The University of Manchester

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Keywords

Chemistry
Materials Science
Spectroscopy
Magnetometry
Redox Biology
Spin-orbit Coupling
X-ray Absorption Spectroscopy
Physics

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About this position

[Fully funded PhD studentship; funding amount not specified.]

This PhD project explores radicals and reactive intermediates in heavy main-group chemistry, with a particular focus on accessing and understanding open-shell species based on heavy pnictogens and related elements. The research aims to develop new routes to authentic main-group radicals and to open-shell fragments such as carbenes, nitrenes, and higher homologues in the vicinity of heavy elements.

The project is centred on inorganic synthesis and advanced spectroscopy. The appointed student will prepare and study novel compounds using Schlenk and glovebox techniques, then investigate their electronic structures and small-molecule reactivity using a broad toolkit of analytical methods. These include NMR, IR, UV/vis, EPR, SQUID, XAS and single-crystal X-ray diffraction.

The research begins with bismuth chemistry, with the possibility of extending to other heavy elements such as antimony, tin, lead, indium, or thallium depending on the results. The studentship is at The University of Manchester and includes co-supervision by experts in inorganic synthesis and magnetism, offering a collaborative environment with opportunities for publication, conference presentation, and wider engagement with researchers across the UK and Europe.

Funding details

Available

What's required

Applicants should hold, or expect to obtain, a First Class or high Upper Second Class degree in Chemistry or a closely related discipline. Prior experience with synthetic chemistry under inert conditions is essential. Experience in spectroscopy of paramagnetic compounds is advantageous but not required.

How to apply

Contact the main supervisor, Dr. Josh Abbenseth, to apply. Include details of your current level of study, academic background, relevant experience, and a paragraph explaining your motivation for the project.

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