Abdelkader T. Ahmed

The ceramic filter amended with iron (Fe) has proven to be a potential low‐cost method for arsenic (As) removal from groundwater. The presence of Fe, phosphate (P), and silicate (Si) significantly affects the As removal efficiency of the ceramic filter, which has not been passably investigated. The present research aimed to examine the effect of Fe, P, and (or) Si presence as single or in combination on As (III) removal from synthetics groundwater by a low‐cost iron amended ceramic filter (IACF). Laboratory‐scale filtration experiments at different compositions of Fe, P, Si, and As (III) were conducted by the IACF fabricated with a ceramic candle and iron netting box. Fe (II) in synthetic groundwater positively impacted As (III) removal. At a concentration of 2 mg/L of Fe (II), the As levels in the effluent decreased to less than the maximum contamination level (MCL) of 50 μg/L. Groundwater P concentration needed less than 3 mg/L or Si concentrations required less than 35 mg/L to effectively reduce As (III) to below the MCL at 5 mg/L of groundwater Fe (II). The cumulative effect of P and Si on As removal was found to be more significant than distinct contributions. The presence of 2 mg/L P and 35 mg/L or higher Si in the groundwater cumulatively reduced the As removal performance from 92% to 63%, and the MCL was not met. The negative impact of P and Si on As (III) removal followed the order of (P + Si) > P > Si. P competed with As for adsorption sites during the process, while Si inhibited the Fe release and floc formation, significantly reducing As removal performance. The study findings can potentially contribute to optimizing IACF as a low‐cost method for As removal from groundwater.

Treating and reusing wastewater is a promising alternative for the water shortage problem. The advanced treatment of such water can provide a good source for plant irrigation and other applications and reduce the demand for the available freshwater resources. This alternate is highly recommended for arid and semi‐arid counties. In this research, volcanic rock (VR) is introduced as an advanced and low‐cost treatment option for wastewater. The volcanic rock was adopted as an adsorption tool for removing impurities from the secondary treated wastewater effluents. The study relies on experimental work on a lab scale. Many parameters were investigated such as loose and compacted layered samples, and pretreated methods for the rocks including soaking in clean water or heating for different temperatures. Simulation work also was adopted to validate the experimental results. The study results showed a decline in most physiochemical properties of wastewater after adding VR compared with the control sample. A notable removable for the measurements of the biological oxygen demand and chemical oxygen demand (COD) from wastewater in the presence of VR was observed, which may introduce it as a tool for the advanced treatment of wastewater. The numerical results depicted the experimental data and reflected the effectiveness of the VR‐based geomaterial filter for the treatment of wastewater. Practitioner Points Prewashing process for volcanic rock (VR) exhibited an improvement in its removal efficiency ranged between 18% to 98% as for TDS and removal of NO 3 − , respectively. Heating samples does not improve the removable properties of VR. A notable removable for biological oxygen demand and COD by 96% and 99%, respectively, for some cases from wastewater, may introduce the VR as a tool for advanced treatment of wastewater. The numerical test results are in consistent with the experimental behavior of the VR and reflect the effectiveness of the VR‐based geomaterial filter for the treatment of wastewater.