Rose L. Ahlefeldt

Double‐negative refractive index materials have attracted sustained experimental and theoretical interest because they can display a range of surprising optical phenomena, including negative Doppler shifts and perfect lensing. Double‐negative indexes have been achieved experimentally in engineered metamaterials; however, these materials become increasingly challenging to fabricate at shorter wavelengths, and at optical wavelengths only 2D negative index materials have been achieved. Here, it is shown that a double‐negative index can occur in a natural material, near narrow optical transitions of dielectric crystals stoichiometric in a rare‐earth ion. Optical measurements of two candidate materials, the magnetically‐ordered erbium crystals, ErCl 3 ·6H 2 O and 7 LiErF 4 , which have ultra‐narrow optical linewidths of 3 GHz and 250 MHz, respectively, in the telecom band are presented. It is shown that the spectral density of 7 LiErF 4 is sufficient to achieve a negative index at 1530 nm. This material can enable the exploration of negative refractive index effects at optical wavelengths in a truly 3D, natural medium.