Takeshi Yasui

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Assistant Professor

Nagoya University

Japan

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About

Dr. Takeshi Yasui is an Assistant Professor at Nagoya University in Japan. His research focuses on catalytic reactions, including the development of new methodologies for bond activation and cycloaddition reactions. Recent publications include investigations into cobalt-catalyzed enantioselective desymmetrization and rhodium-catalyzed reactions, contributing significantly to the fields of organic synthesis and catalysis.

Recent Grants

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コバルト/光レドックス協働触媒が拓くσ結合活性化を伴う環化異性化反応

Open Date: 2021-04-01

Close Date: 2024-03-01

Grant: Close

遷移金属触媒を用いる光学活性らせん性環状エキソジエン合成法の開発

Open Date:

Close Date:

Grant: Close

炭素-炭素結合活性化を鍵とする新規環化異性化反応の開発

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Close Date:

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2025

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2022

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2022

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2022

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2021

Collaborators (5)

Nobuaki Koga

Nagoya University

JAPAN

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Shigeki Takeda

JAPAN

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Masashi Watanave

Gunma University

JAPAN

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Hirokazu Hirai

Professor & Chair

Gunma University Graduate School of Medicine

JAPAN

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Yoshihiko Yamamoto

Professor

Nagoya University

JAPAN

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Takeshi Yasui

Research Interests

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About

Recent Grants

Articles (20)

Rh(III)-Catalyzed Oxidant-Free Dehydrogenative Mizoroki–Heck-Type Reaction: Identification of Off-Cycle Processes Potentially Limiting Catalytic Turnover

Synthesis of Spirocyclic Phthalans via Ru-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Diynes with Ex-Situ Generated Acetylene

Cobalt-Catalyzed Enantioselective Desymmetrization and Chemodivergent Parallel Kinetic Resolution of Unsaturated Substrates via C(sp<sup>3</sup>)–H Bond Activation

Electrochemical Decarboxylative Trifluoromethylation of Cinnamic Acids Revisited: A Combined Experimental and Computational Study

Dearomative Transformation of Pyridin-3-ols into 2,3,6,7-Tetrahydro-1<i>H</i>-2,6-methanobenzo[<i>d</i>]azonin-12-ones via Oxidopyridinium/<i>o</i>-Quinodimethane (5 + 4) Cycloaddition

Kinetic resolution of trifluoromethylated heterobenzhydrols <i>via</i> hydrogen-acceptor-free Ir-catalyzed heteroaryl-selective C–H silylation

Cobalt/Photoredox Cooperative Catalysis‐Enabled Cycloaddition Reactions of 1,6‐Diynes and Related Compounds

Enantioselective Desymmetrization of Trifluoromethylated Tertiary Benzhydrols via Hydrogen-Acceptor-Free Ir-Catalyzed Dehydrogenative C–H Silylation: Decisive Role of the Trifluoromethyl Group

Cobalt/Organophotoredox Dual-Catalysis-Enabled Cyclization of 1,5,10-Enediynes Involving Metallole-Mediated Remote C(sp3)–H Bond Activation Leading to Axially Chiral Aryl Alkenes

Cycloaddition of Cyclopropenes with Alkynes via Carbon–Carbon Double Bond Cleavage Enabled by a Ruthenium Catalyst: Synthesis of Cyclopentadienes and Cycloheptatrienes

Trifluoromethylated Oxidopyridinium Betaines: Unique (5+2) Cycloaddition Selectivity Imposed by 2‐ or 6‐Trifluoromethyl Groups

Concise Synthesis of Functionalized Cyclopentadienyl Rhodium(III) Complexes via Suzuki–Miyaura Cross Coupling

Oxidopyridinium Cycloadditions Revisited: A Combined Computational and Experimental Study on the Reactivity of 1-(2-Pyrimidyl)-3-oxidopyridinium Betaine

Rh(III)-Catalyzed Highly Site- and Regio-Selective Alkenyl C–H Activation/Annulation of 4-Amino-2-Quinolones with Alkynes via Reversible Alkyne Insertion

Construction of Diverse Polycyclic Structures via Group 9 Metal-Catalyzed Cycloisomerization of 1,6-Diyne Derivatives

生物活性分子にみられる多環式骨格の一挙構築を可能にする触媒的環化異性化反応の開発

Development of novel potent ligands for GPR85, an orphan G protein-coupled receptor expressed in the brain

Combined Computational and Experimental Study on [5 + 2] Cycloaddition of 2-Trifluoromethylated Oxidopyrylium Species Leading to 1-(Trifluoromethyl)-8-oxabicyclo[3.2.1]oct-3-en-2-ones

Co-Catalyzed atom transfer radical addition of bromodifluoroacetamides, expanding the scope of radical difluoroalkylation

Catalyst‐Free Csp−Csp3 Cross‐Coupling of Bromodifluoroacetamides with 1‐Iodoalkynes under Visible‐Light Irradiation

Collaborators (5)

Nobuaki Koga

Shigeki Takeda

Masashi Watanave

Hirokazu Hirai

Yoshihiko Yamamoto

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