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University of Birmingham
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CENTA 2027-B14 PhD Studentship in Atmospheric Chemistry of Hydrofluoroolefins: Spectroscopic and Computational Studies of Fluorinated Criegee Intermediates University of Birmingham in United Kingdom
Degree Level
PhD
Field of study
Chemistry
Funding
Available
Deadline
Jan 6, 2027
Country
United Kingdom
University
University of Birmingham
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About this position
This PhD studentship investigates the atmospheric chemistry of hydrofluoroolefins (HFOs), a new class of refrigerants replacing older halocarbons in applications such as automotive air conditioning and heat pumps. The project addresses a major knowledge gap in how these compounds break down in the atmosphere, with particular attention to nighttime ozonolysis and the formation of highly reactive fluorinated Criegee intermediates.
The student will combine laboratory spectroscopy with computational chemistry to uncover the structures and reactivity of these short-lived intermediates. Experiments will use advanced laser-based techniques designed for selective detection of trace reactive species, enabling the first direct spectroscopic characterisation of fluorinated Criegee intermediates. Alongside the laboratory work, high-level quantum chemical calculations and master-equation modelling will be used to map reaction pathways and conformer-specific behaviour.
The project is interdisciplinary, bridging physical chemistry, atmospheric chemistry, and modelling. A key outcome will be the incorporation of results into the Master Chemical Mechanism, supporting broader atmospheric simulation and urban air-quality studies. The work has relevance for understanding oxidative budgets, ozone formation, secondary organic aerosol production, and the atmospheric fate of HFOs.
The studentship is hosted by the University of Birmingham as part of the CENTA3 Doctoral Landscape Award network.
Funding details
Available
What's required
Applicants should have at least a 2:1 degree at UK BSc level or a pass at UK MSc level, or an equivalent qualification. International applicants must meet the University of Birmingham’s international student entry requirements, including English language requirements. International students are eligible for studentships up to 30% of the cohort.
How to apply
Click the Apply button on the advert to start the application. For general CENTA studentship application guidance, follow the CENTA apply page. Check the University of Birmingham international student entry requirements if applicable.
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